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Notation and terminology: phase space

In a system of N classical point particles, for each particle i there will be a position vector tex2html_wrap_inline737 and its canonically conjugate momentum vector tex2html_wrap_inline739 . Decomposing these vectors into Cartesian coordinates gives tex2html_wrap_inline741 and tex2html_wrap_inline743 . For all N particles, a useful notation for position is tex2html_wrap_inline747 , and for momentum tex2html_wrap_inline749 . For extended particles each particle will have additional internal coordinates and their canonically conjugate momenta. The complete set of Hamiltonian coordinates of a system is tex2html_wrap_inline751 . For a function, the corresponding notation is tex2html_wrap_inline753

A point particle requires 6 coordinates tex2html_wrap_inline755 for its complete description, so an N-particle set of point particles is characterized by 6N coordinates. Non-point particles, such as most molecules, require some number m (m > 6) coordinates to be described, so for N extended particles mN coordinates are needed. Just as the three position coordinates (x, y, z) of a pointlike atom can be envisioned as a point in a 3-dimensional space, so also the 6N coordinates needed to describe N pointlike particles can be imagined as a single point in a 6N-dimensional space. This 6N-dimensional space is known as phase space. A single point in phase space corresponds to a list of the values of 6N-coordinates. Since the position of the point in phase space fixes the 6N variables that comprise a complete microscopic description of the system, each point in phase space corresponds uniquely to a single state of the system, and vice versa: every allowed point in phase space corresponds to a state of the system. A ``point in phase space'' is known as a phase point, whose customary notation is tex2html_wrap_inline781 . The value of tex2html_wrap_inline783 , i. e. the precise state of the system, was called by Gibbs the configuration in phase. (For extended particles, the 6N-dimensional phase space is replaced by an mN-dimensional phase space.) An integral over all 6N coordinates of phase space is a phase space integral. The subspace spanned by tex2html_wrap_inline791 is known as position space; the subspace spanned by tex2html_wrap_inline793 is known as momentum space.

For a system of allowed volume V the volume integral has a simplified notation

  equation211

the rhs being compressed notation for a triple integral over a volume. A further compression expresses an integral over all the particle coordinates, namely

  equation221

An identical series of replacements transform the integral over particle momenta, namely

  equation236

The tex2html_wrap_inline807 is a three-dimensional integral, whose implicit bounds range from tex2html_wrap_inline809 to tex2html_wrap_inline811 in all directions. Also in use is the notation

  equation252

This notation will appear gradually in future Lectures.


next up previous
Next: Summary Up: Chapter 3 Previous: Other Ensembles

Nicholas V Sushkin
Sat Jun 29 21:50:24 EDT 1996